We prove, under some mild conditions, that the equivariant twisted K-theory group of a crossed module admits a ring structure if the twisting 2-cocycle is 2-multiplicative. We also give an explicit construction of the transgression map for any crossed module and prove that any element in the image is -multiplicative. As a consequence, we prove that, under some mild conditions, for a crossed module and any $e \in \check{Z}^3(\Gamma;S^1)K^*{e,\Gamma}(N)$ admits a ring structure. As an application, we prove that for a compact, connected and simply connected Lie group G, the equivariant twisted K-theory group is endowed with a canonical ring structure $K^{i+d}{[c],G}(G)\otimes K^{j+d}{[c],G}(G)\to K^{i+j+d}{[c], G}(G)d=dim G[c]\in H^2(G\rtimes G;S^1)$.

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