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In this paper, we study commutative zero-divisor semigroups determined by graphs. We prove a uniqueness theorem for a class of graphs. We show two classes of graphs that have no corresponding semigroups. In particular, any complete graph together with more than three end vertices and any complete bipartite graph together with more than one end vertices have no corresponding semigroups. We also determine all possible zero-divisor semigroups whose zero-divisor graph is the com- plete graph together with two end vertices.

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