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The operad Lie can be constructed as the operad of primitives Prim As from the operad As of associative algebras. This is reflected by the theorems of Friedrichs, Poincare’-Birkhoff-Witt and Cartier-Milnor-Moore. We replace As by families of free operads P, which include the operad Mag freely generated by a noncommutative non-associative binary operation and the operad of Stasheff polytopes. We obtain Poincare’-Birkhoff-Witt type theorems and collect information about the operads Prim P, e.g. in terms of characteristic functions.

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