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We use the theory of motivic integration for singular spaces to give a characterization of minimal log discrepencies in terms of the codimension of certain subsets of spaces of arcs. This is done for arbitrary pairs , with normal and Q-Gorenstein. As a first application, we prove a precise version of Inversion of Adjunction, in the case when the ambient variety is smooth. Another application concerns the semicontinuity of minimal log discrepancies on smooth varieties.

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