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In angular quantization approach a perturbation theory for the Massive Thirring Model (MTM) is developed, which allows us to calculate Vacuum Expectation Values of exponential fields in sin-Gordon theory near the free fermion point in first order of MTM coupling constant . The Hankel-transforms play an important role when carrying out this calculations. The expression we have found coincides with that of the direct expansion over of the exact formula conjectured by S.Lukyanov and A.Zamolodchikov.

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