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Extended Schwinger’s quantization procedure is used for constructing quantum mechanics on a manifold with a group structure. The considered manifold is a homogeneous Riemannian space with the given action of isometry transformation group. Using the identification of with the quotient space , where is the isotropy group of an arbitrary fixed point of , we show that quantum mechanics on possesses a gauge structure, described by the gauge potential that is the connection 1-form of the principal fiber bundle $G(G/H, H)$. The coordinate representation of quantum mechanics and the procedure for selecting the physical sector of states are developed.

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