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The classical first law of thermodynamics for a Kerr-Newman black hole (KNBH) is generalized to a law in quantum form on the event horizon. Then four quantum conservation laws on the KNBH equilibrium radiation process are derived. The Bekenstein-Hawking relation is exactly established. It can be inferred that the classical entropy of black hole arises from the quantum entropy of field quanta or quasi-particles inside the hole.

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