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The constituent quark model symmetry of the light diquark system are used to analyze single pion transitions of S-wave to S-wave and P-wave to S-wave heavy baryons. We show that the Heavy Quark Symmetry (HQS) coupling factors are given in terms of the three independent couplings and . Light-Front quark model spin wave functions are, then, employed to calculate these couplings and to predict decay rates of single pion transitions between charm baryon states.

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