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We properly define off-shell transition amplitudes and use them to extract information for on-shell amplitudes within Chiral Perturbation Theory. At order in the chiral expansion all three parameters of weak interaction can be determined. At order we are able to fix eleven additional constants out of thirteen contributing to off-shell transitions, which leaves four undetermined constants in the on-shell amplitudes. All contributions have been exactly derived with . We finally discuss the weak mass term issue and find contributions to on-shell Kaon decays, in particular to transitions like , and $K_S \to \pi^0 \gamma \gamma$ at the lowest non-zero order.

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