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Non-leading contribution to the pion electromagnetic form factor which comes from the pion twist-3 wave function is analyzed in the modified hard scattering approach (MHSA) proposed by Li and Sterman. This contribution is enhanced significantly due to bound state effect (the twist-3 wave function is independent of the fractional momentum carried by the parton and has a large factor with being the pion meson mass and being the mean u- and d-quark masses). Consequently, although it is suppressed by the factor , the twist-3 contribution is comparable with and even larger than the leading twist (twist-2) contribution at intermediate energy region of being .

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