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In the framework of the quasipotential method we calculate the contributions of the kind \alpha^6\ln\alpha, alpha^6 of three-photon exchange diagrams to the energy spectrum of muonium state in the leading order on . Analytical expression of obtained correction for arbitrary principal quantum number is equal to (Z\alpha)^6(m_e/m_\mu)m_e(6\ln(2)-35/48)/n^3.

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