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The photon pair production by pion annihilation in a hot and dense medium at the chiral phase transition is investigated within a chiral quark model. As a direct consequence of this transition the meson appears as a bound state in the domain of temperatures and chemical potentials where the condition is fulfilled. This effect results in a strong enhancement of the cross section for the pion annihilation process $2 \pi \to 2 \gamma$ compared with the vacuum case. The calculation of the photon pair production rate as function of the invariant mass shows a strong enhancement and narrowing of the meson resonance at threshold due to chiral symmetry restoration.

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