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We present the complete O(alpha_s^2) corrections to the Wilson coefficient of the unit operator in the zero-recoil sum rule for the B–>D* transition. We include both perturbative and power-suppressed nonperturbative effects in a manner consistent with the operator product expansion. The impact of these corrections on |V_cb| extracted from semileptonic B–>D* decays near zero recoil is discussed. The mixing of the heavy quark kinetic operator with the unit operator at the two loop level is obtained. O(alpha_s) corrections to a number of power-suppressed operators are calculated.

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