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Using the PQCD method we calculate the W-exchange and the W-annihilation processes of B mesons, which in general involve a charm quark or anti-quark in the final state. The nonvanishing amplitudes of these processes are found to be suppressed by a factor of compared to the tree or the time-like penguin processes, but some of them are within the reach of observation at the future B-factories, and whose branching ratio is found to be can be found even before the B-factory era. Comparisons with the results based on the BSW model are also given.

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