The long distance vector-meson-dominance (VMD) effects on the weak radiative decays and are studied. For decays, the VMD contribution is of the short-distance penguin amplitude. The pole effect is as important as the VMD one in the decay , but it is suppressed in $\bb^0\to \rho^0\gamma\bb\to\rho\gamma$, estimated to be of order , strongly depends on the sign of the Wolfenstein parameter . A measurement of any deviation of the ratio $R=\Gamma(B^-\to\rho^- \gamma)/\Gamma(\bb^0\to\rho^0\gamma)$ away from the isospin value 2 will not only provide a probe on the long-range contribution but also fix the sign of : for and for . The decay $\bb^0\to D^{*0}\gamma$ does not receive short-distance contributions, and its branching ratio, predicted to be , is dominated by -exchange accompanied by a photon emission.

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