We calculate the and couplings using QCD sum rules on the light-cone. In this approach, the large-distance dynamics is incorporated in a set of pion wave functions. We take into account two-particle and three-particle wave functions of twist 2, 3 and 4. The resulting values of the coupling constants are and . From this we predict the partial width $ \Gamma (D^{*+} \ra D^0 \pi^+ )=32 \pm 5~ keV $. We also discuss the soft-pion limit of the sum rules which is equivalent to the external axial field approach employed in earlier calculations. Furthermore, using and the pole dominance model for the and semileptonic form factors is compared with the direct calculation of these form factors in the same framework of light-cone sum rules.

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