The recent surprising discovery of superconductivity with critical temperature = 32 K in MoB above 70 GPa has led to the search for related materials that may superconduct at similarly high values and lower pressures. We have studied the superconducting and structural properties of ReMoB to 170 GPa. A structural phase transition from R3m to P6/mmm commences at 48 GPa, with the first signatures of superconductivity appearing above 44 GPa. The critical temperature is observed to increase with pressure. A complete resistive transition is observed only above 150 GPa, where the highest onset of 30 K is also achieved. Upon releasing pressure, the high pressure superconducting phase is found to be metastable. During unloading, a complete resistive superconducting transition is observed all the way down to 20 GPa (with onset K). Our results suggest that the P6/mmm structure is responsible for the observed superconductivity.

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