We study the charmless rare decays within the Perturbative QCD picture. We calculate not only factorizable and non-factorizable diagrams, but also annihilation ones. Our predictions are the following: The longitudinal polarization fraction vary from 75% to 99% depending on channels, the branching ratios are of order for and $B^{\pm} \to K^{\ast\pm} \bar{K}^{\ast0}(K^{\ast0})B^0(\bar{B}^0) \to K^{\ast+}K^{\ast-}10^{-8}B^{\pm} \to K^{\ast\pm} \bar{K}^{\ast0}(K^{\ast0})B^0(\bar{B}^0) \to K^{\ast+}K^{\ast-}\alpha (\phi_2)95^{\circ}B^0(\bar{B}^0) \to K^{\ast0}\bar{K}^{\ast0}b \to d$ penguin topology. Our predictions will be tested in the future B experiments.

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