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We discuss the exclusive radiative decays B -> K* gamma and B -> rho gamma in QCD factorization within the Standard Model. The analysis is based on the heavy-quark limit of QCD. Our results for these decays are complete to next-to-leading order in QCD and to leading order in the heavy-quark limit. Phenomenological implications for branching ratios and isospin breaking effects are discussed. Special emphasis is placed on constraining the CKM unitarity triangle from these observables.

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