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We present the first study of the rare annihilation decay $\bar{B}^0_d \to \phi\gamma{\cal B}(\bar{B}^0_d \to\phi\gamma)=3.6\times 10^{-12}$. The smallness of the decay rate in the Standard Model make the decay a sensitive probe of new physics contributions. As an example, we calculate the effects of R-parity violating couplings. Within the available upper bounds for and , could be enhanced to order of , which might be accessible at LHCB, B-TeV and the planning super high luminosity B factories at KEK and SLAC.

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