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We study the temperature dependence of the eta and eta’ meson masses within the framework of U(3)_L x U(3)_R chiral perturbation theory, up to next-to-leading order in a simultaneous expansion in momenta, quark masses and number of colours. We find that both masses decrease at low temperatures, but only very slightly. We analyze higher order corrections and argue that large N_c suggests a discontinuous drop of M_eta’ at the critical temperature of deconfinement T_c, consistent with a first order transition to a phase with approximate U(1)_A symmetry.

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