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A systematic approach to long-distance effects in exclusive radiative weak decays is presented, based on a combination of the heavy quark limit with perturbative QCD. The dominant long-distance effects, connected with weak annihilation and -exchange topologies, can be computed in a model-independent way using experimental data on radiative leptonic decays. Nonfactorizable corrections vanish in the chiral limit and to leading twist. The left-handed photon amplitudes are shown to be enhanced relative to the right-handed ones, both in the long- and short-distance parts of the decay amplitudes. We discuss the implications of our results for the extraction of .

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