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It is pointed out that one-component \phi^4 lattice theory in four dimensions has a non-perturbative sector which can be studied by means of an exact duality transformation of its Ising limit. This duality maps it to a membrane model. As a consequence, the \phi^4-theory turns out to have, in the broken symmetry phase, a remarkably rich spectrum of physical states corresponding to membrane excitations. A numerical study of the correlators between dual variables allows to evaluate the masses of the first few states.

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