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We carry out a high-precision simulation of the two-dimensional principal chiral model at correlation lengths up to $\approx! 4 \times 10^5$, using a multi-grid Monte Carlo (MGMC) algorithm. We extrapolate the finite-volume Monte Carlo data to infinite volume using finite-size-scaling theory, and we discuss carefully the systematic and statistical errors in this extrapolation. We then compare the extrapolated data to the renormalization-group predictions. For we observe good asymptotic scaling in the bare coupling; at the nonperturbative constant is within 2–3% of its predicted limiting value.

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