In the paper we study the existence of balanced metrics of Hodge-Riemann type on non-Kähler complex manifolds. We first find some general obstructions, for instance that a Hodge-Riemann balanced manifold of complex dimension has to be -Kähler. Then, we focus on the case of compact quotients of Lie groups by lattices, endowed with an invariant complex structure. In particular, we prove non existence results on non-Kähler complex parallelizable manifolds and some classes of solvmanifolds, and we show that the only nilmanifolds admitting invariant structures of this type are tori. Finally, we construct the first non-Kähler example of a Hodge-Riemann balanced structure, on a non-compact complex manifold obtained as the product of the Iwasawa manifold by .

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