We investigate the dynamics of multipartite entanglement after quenches from initial states which generate multiplets of quasiparticle excitations beyond the usual pair structure. We focus on the dynamics of tripartite entanglement through the lens of the Markov gap – a computable quantity that signals irreducible tripartite entanglement when positive. In the XX spin chain, we show that the Markov gap is positive at intermediate times, implying the presence of tripartite entanglement. After a time delay, the Markov gap increases and then decays at longer times, thus exhibiting an entanglement barrier. We argue that those qualitative features are consistent with an interpretation of the spreading of tripartite entanglement by triplets of tripartite-entangled quasiparticles.

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