Let be a closed surface, a compact Lie group, with Lie algebra , and a principal -bundle. In earlier work we have shown that the moduli space of central Yang- Mills connections, for appropriate additional data, is stratified by smooth symplectic manifolds and that the holonomy yields a diffeomorphism from onto a certain representation space , with reference to suitable smooth structures and where denotes the universal central extension of the fundamental group of . Given an invariant symmetric bilinear form on , we construct here Poisson structures on and in such a way that the mentioned diffeomorphism identifies them. When the form on is non-degenerate the Poisson structures are compatible with the stratifications where is endowed with the corresponding stratification and, furthermore, yield structures of a {\it stratified symplectic space/}, preserved by the induced action of the mapping class group of .

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