Stiffening Transition in Vicinal Surfaces with Adsorption

We study the vicinal surface with adsorption below the roughening temperature, using the restricted solid-on-solid model coupled with the Ising model. We calculate the step tension $\gamma$ and the step-interaction coefficient $B$ by employing a variant of the density matrix algorithm. We find a ``stiffening transition’’ at a temperature $T_{\mathrm{s}}$ where $B$ vanishes. At $T_{\mathrm{s}}$ surface free energy has the form $f(p)- f(0)= \gamma p + ({const.})p^5 + …$($p$:surfacegradient),whichdiffersfromthewell-known$p$-$p^3$ form.