In a superconductor coupled with a ferromagnetic metal, spin and charge imbalances can be induced by injecting spin-polarized electron current from the ferromagnetic metal. We theoretically study a nonequilibrium distribution of quasiparticles in the presence of spin and charge imbalances. We show that four distribution functions are needed to characterize such a nonequilibrium situation, and derive a set of linearized Boltzmann equations for them by extending the argument by Schmid and Sch"{o}n based on the quasiclassical Green’s function method. Using the Boltzmann equations, we analyze the spin imbalance in a thin superconducting wire weakly coupled with a ferromagnetic electrode. The spin imbalance induces a shift () of the chemical potential for up-spin (down-spin) quasiparticles. We discuss how is relaxed by spin-orbit impurity scattering.

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