We study the dynamical properties of a diffusing lamb captured by a diffusing lion on the complex networks with various sizes of . We find that the life time <T> and the survival probability $S(N\to \infty,t)\gamma>3S(N,t)\gamma<3$ has a long-living tail on tree-structured scale-free networks and decays exponentially on looped scale-free networks. It suggests that the second moment of degree distribution <k^2>$ is the relevant factor for the dynamical properties in diffusive capture process. We numerically find that the normalized number of capture events at a node with degree , , decreases as . When , still increases anomalously for . We analytically show that satisfies the relation and the total number of capture events is proportional to <k^2>$, which causes the dependent behavior of and <T>$.

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