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We report the measurements of thermopower, electrical resistivity and thermal conductivity in a complex cobalt oxide LiNaCoO, whose crystal structure can be viewed as an intergrowth of the O3 phase of LiCoO and the P2 phase of NaCoO along the c axis. The compound shows large room-temperature thermopower of 180 V/K, which is substantially higher than those of LiCoO and NaCoO. The figure of merit for the polycrystalline sample increases rapidly with increasing temperature, and it achieves nearly 10 K at 300 K, suggesting that LiNaCoO system is a promising candidate for thermoelectric applications.

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