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We report direct evidence of charge/orbital ordering of low energy electronic states of in YBaCuO ortho-II phase in both the chain and the CuO plane. Huge enhancement of the superstructure Bragg peak is observed when photon energy is tuned to the $Cu L_{2,3}$ absorption edge with large polarization dependence. The ordering in the plane discovered here sheds new light on how the one dimensional chains affect the plane, and why many normal and superconducting state properties of this system exhibit strong anisotropy.

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