Structural study of Cu${}_{2-x}$Se alloys produced by mechanical alloying

The crystalline structures of superionic high temperature copper selenides Cu${}_{2-x}$Se ($0\le x\le 0.25$) produced by Mechanical Alloying were investigated using X-ray diffraction (XRD) technique. The measured XRD patterns showed the presence of the peaks corresponding to the crystalline superionic high temperature $\alpha$-Cu${}_2$Se phase in the as-milled sample, and its structural data were determined by means of a Rietveld refinement procedure. After a heat treatment in argon at 200${}^{\circ }$C for 90 h, this phase transforms to the superionic high temperature $\alpha$-Cu${}_{1.8}$Se phase, whose structural data where also determined through the Rietveld refinement. In this phase, a very low occupation of the trigonal 32(f) sites ($\sim 3$%) by Cu ions is found. In order to explain the evolution of the phases in the samples, two possible mechanisms are suggested: the high mobility of Cu ions in superionic phases and the intense diffusive processes in the interfacial component of samples produced by Mechanical Alloying.