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We report studies of polycrystalline samples of the metallic ferromagnet Pr0.5Sr0.5CoO3 through measurements of the magnetization, a.c. magnetic susceptibility, resistivity, and specific heat. We find an unusual anomaly around TA = 120 K, much below the ferromagnetic transition (TC = 226 K). The anomaly is manifested in field cooled magnetization as a downward step in low fields (H less than or equal to 0.01 T) but is transformed into an upward step for H greater than or equal to 0.05 T. The anomaly cannot be easily attributed to antiferromagnetic ordering, but may correspond to a second ferromagnetic transition or an alteration of the ferromagnetic state associated with orbital ordering.

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