Using the nonequilibrium Green function, we show that microwave irradiation can reverse the supercurrent flowing through a superconductor / quantum-dot / superconductor structure. In contrast with the conventional sideband effect in normal-metal / quantum-dot / normal-metal junctions, the photon-assisted structures appear near , where is the resonant energy level of the quantum dot and is the frequency of microwave field. Each photon-assisted structure is composed of a negative and a positive peak, with an abrupt jump from the negative peak to the positive peak around . The microwave-induced -junction transition is interpreted in the picture of photon-assisted Andreev bound states, which are formed due to multiple photon-assisted Andreev reflection between the two superconductors. Moreover, the main resonance located at can also be reversed with proper microwave strength and frequency.

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