We report B-NMR study on Al-doped MgB that addresses a possible mechanism for a high superconducting (SC) transition temperature () of K in recently discovered MgB. The result of nuclear spin lattice relaxation rate in the SC state revealed that the size in the SC gap is not changed by substituting Al for Mg. The reduction on by Al-doping is shown to be due to the decrease of . According to the McMillan equation, the experimental relation between and the relative change in allowed us to estimate a characteristic phonon frequency $\omega \sim 700\lambda \sim 0.87$. These results suggest that the high- superconductivity in MgB is mediated by the strong electron-phonon coupling with high-frequency phonons.

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