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We investigate analytically and numerically Bloch waves for a Bose–Einstein condensate in a sinusoidal external potential. At low densities the dependence of the energy on the quasimomentum is similar to that for a single particle, but at densities greater than a critical one the lowest band becomes triple-valued near the boundary of the first Brillouin zone and develops the structure characteristic of the swallow-tail catastrophe. We comment on the experimental consequences of this behavior.

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