The influence of dispersion-less quantum optical phonons on the phase diagram of a quarter-filled Hubbard chain is studied using the Density-matrix renormalization group technique. The ground state phase diagram is obtained for frequencies corresponding to the intra-molecular vibrations in organic conductors. For high vibrational modes the system is only slightly affected by the electron-phonons coupling. It remains in a L"uttinger liquid phase as long as the electronic repulsion is larger than the polaronic binding energy. For low vibrational modes the phase diagram is very rich. A noticeable point is the existence of a CDW phase for small values of the correlation strength. For realistic values of the electron repulsion and of the electron-phonons coupling constant a large phonons-mediated reduction of the L"uttinger liquid parameter was found compared to the pure electronic model.

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