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Weak ferromagnetism of quasi-one-dimensional S = 1/2 antiferromagnet BaCuGeO is studied by the magnetization measurement. The spontaneous magnetization appears along the b axis. The local symmetry between the in-chain nearest neighbor spins allows the presence of Dzyaloshinskii-Moriya interaction, and the only possible spatial configuration of the weak ferromagnetic moment per spin determines the sign of the inter-chain interaction. A weak -axis magnetic field can change the direction of the magnetization to the -axis direction, which shows that the spin chain forms a weakly coupled weak-ferromagnetic chain system.

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