We investigate symmetry properties of the Bethe ansatz wave functions for the Heisenberg spin chain. The Hamiltonian commutes simultaneously with the shift operator and the lattice inversion operator in the space of with the eigenvalue of . We show that the Bethe ansatz solutions with normalizable wave functions cannot be the eigenstates of and with quantum number where is the eigenvalue of . Therefore the Bethe ansatz wave functions should be singular for nondegenerate eigenstates of the Hamiltonian with quantum number . It is also shown that such states exist in any nontrivial down-spin number sector and that the number of them diverges exponentially with the chain length.

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