Temperature Dependence of the Optical Response of Small Sodium Clusters

We present an analysis of the temperature dependence of the optical response of small sodium clusters in a temperature range bracketing the melting phase transition. When the temperature increases, the mean excitation energy undergoes a red shift and the plasmon is significantly broadened, in agreement with recent experimental data. We show that the single–particle levels acquire a prominent width and the HOMO–LUMO gap as well as the width of the occupied band are reduced due to large thermal cluster size and shape fluctuations. This results in a sharp increase of the static polarizability with temperature.