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We describe the dynamical behavior found in numerical solutions of the Vector Complex Ginzburg-Landau equation in parameter values where plane waves are stable. Topological defects in the system are responsible for a rich behavior. At low coupling between the vector components, a {\sl frozen} phase is found, whereas a {\sl gas-like} phase appears at higher coupling. The transition is a consequence of a defect unbinding phenomena. Entropy functions display a characteristic behavior around the transition.

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