Neutron-rich P, Cl, and K isotopes, particularly those with neutron numbers around , have attracted extensive experimental and theoretical interest. We utilize the valence-space in-medium similarity renormalization group approach, based on chiral nucleon-nucleon and three-nucleon forces, to investigate the exotic properties of these isotopes. Systematic calculations of the low-lying spectra are performed. A key finding is the level inversion between and states in odd- isotopes, attributed to the inversion of and single-particle states. calculations, which incorporate the three-nucleon forces, correlate closely with existing experimental data. Further calculations of effective proton single-particle energies provide deeper insights into the shell evolution for and sub-shells. Our results indicate that the three-body force plays important roles in the shell evolution for and sub-shells with neutron numbers ranging from 20 to 28. Additionally, systematic calculations are conducted for the low-lying spectra of odd-odd nuclei. The results align with experimental data and provide new insights for future research into these isotopes, up to and beyond the drip line.

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