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The first detection of a S-bearing molecule in interstellar space is reported. The = and transitions of CS have been observed toward eight Galactic molecular hot cores. From a comparison with other optically thin isotopic species of CS, the abundance ratio of S/S is 115. This is smaller than the solar system ratio of 200 and supports the idea that S is, unlike the other stable sulfur isotopes, a purely secondary nucleus that is produced by s-process nucleosynthesis in massive stars.

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