The imaging atmospheric Cherenkov array H.E.S.S. recently discovered an extended source in the 0.410 TeV energy range, HESS J1303-631. We obtained a 5 ks observation with the ACIS-I array on the Chandra X-ray observatory that does not reveal an obvious compact or diffuse X-ray counterpart. Archival ROSAT images are also blank in this region. Although there are several radio pulsars within the field of HESS J1303-631, none is detected in X-rays to a flux limit of ergs cm s, and none is a likely counterpart on energetic grounds. Over the entire $17^{\prime} \times 17^{\prime}<5.4 \times 10^{-12}^{-2}^{-1}$ on the excess diffuse flux in the 2-10 keV band. One hard point-source with flux ergs cm s lies within of the centroid of the TeV emission. These exploratory observations suggest that deeper pointings with Chandra and XMM are needed before we can learn more about the nature of HESS J1303-631. Its similarity to the unidentified source TeV J2032+4130 indicates the probable existence of a new class of high-energy source in the Galactic plane that originates from young, massive stars or their supernova remnants.

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