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A model of a hydrogenic content of atmosphere of the isolated neutron star 1E1207.4-5209 is proposed. It is based on the assumption that the main component in the atmosphere is the exotic molecular ion and that there exists a magnetic field in the range of G. Photoionization and photodissociation $H_3^{2+} \rar H + 2p$ correspond to two absorption features at 0.7 KeV and 1.4 KeV, respectively, discovered by {\it Chandra} observatory (Sanwal et al, 2002). The model predicts one more absorption feature at 80-150 eV corresponding to photodissociation .

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