We report the first detection of the reactive ions CO+ and HOC+ towards ultracompact (UC) HII regions, particularly in Mon R2 and G29.96-0.02. We have observed two positions in Mon R2, namely the peak of the UC HII region and a position in the high density molecular cloud which bounds it. CO+ and HOC+ were detected at the UC HII region but not at the molecular cloud, as expected if the CO and HOC emissions arise in the PDR surrounding the \uch. The measured CO and HOC column densities are of the order of 10 cm in both sources, which yields a strikingly low [HCO]/[HOC] abundance ratio of 460 in Mon R2. These values are similar to those found in some other well-known PDRs, like NGC 7023 and the Orion Bar. We briefly discuss the chemical implications of these results.

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