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High-resolution optical spectra of the R Coronae Borealis (RBC) star V854 Centauri in the early stages of a decline show, in addition to the features reported for other RCBs in decline, narrow absorption lines from the C_2 Phillips system. The low rotational temperature, T_rot = 1150K, of the C_2 ground electronic state suggests the cold gas is associated with the developing shroud of carbon dust. These absorption lines were not seen at a fainter magnitude on the rise from minimum light nor at maximum light. This is the first detection of cold gas around a RCB star.

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