Graph-based analysis holds both theoretical and applied significance, attracting considerable attention from researchers and yielding abundant results in recent years. However, research on fractional problems remains limited, with most of established results restricted to lattice graphs. In this paper, fractional Sobolev spaces are constructed on general graphs that are connected, locally finite and stochastically complete. Under certain assumptions, these spaces exhibit completeness, reflexivity, and other properties. Moreover, we propose a fractional -Laplace operator, and study the existence of solutions to some nonlinear Schrödinger type equations involving this nonlocal operator. The main contribution of this paper is to establish a relatively comprehensive set of analytical tools for studying fractional problems on graphs.

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