We examine the behavior of tree-level scattering in thermal QCD at high energies and find significant deviations away from the commonly used approximations [Phys. Rev. D 44, 1298 (1991), Phys. Rev. D 44, R2625 (1991), Phys. Rev. D.77, 014015 (2008), Phys. Rev. D. 77.114017 (2008)]. These deviations in the scattering rate also affect jet-medium transport coefficients at the partonic level, leading to a different kinematic dependence of the transverse momentum broadening per unit length . As scattering rates and are used by large-scale Monte Carlo simulations of jets in the quark-gluon plasma (QGP), such as [Phys. Rev. C 111,054913 (2025)], current constraints on are biased owing to the approximations used therein. Besides theoretically improving , the differences between the herein and the approximate used in jet Monte Carlo simulations are used to construct a theoretical systematic uncertainty, which in turn can be employed to devise a covariance matrix for and enables updating the uncertainty bands on obtained by Bayesian analysis.

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